Wednesday, April 30, 2008

Tephrochronology


Tephrochronology is a geochronological technique that utilises discrete layers of tephra—volcanic ash from a single eruption—to create a chronological framework in which palaeoenvironmental or archaeological records can be placed. Such an established event provides a "tephra horizon". Each volcanic event has a unique chemical 'fingerprint' that is identifiable in its fallout.
The main advantages of the technique are that the volcanic ash layers can be relatively easily identified in many sediments and that the tephra layers are deposited relatively instantaneously over a wide spatial area. This means they provide accurate temporal marker layers which can be used to verify or corroborate other dating techniques, linking sequences widely separated by location into a unified chronology that correlates climactic sequences and events.
The problems associated with tephochronology are that its use has been limited to areas of frequent large-scale volcanic activity and that tephra chemistry can become altered over time. It also requires accurate geochemical fingerprinting (usually via an electron microprobe) and radiometric dating of proximal tephra deposits.
Early tephra horizons were identified with the Saksunarvatn tephra (Icelandic origin, ca 10.2 cal. ka BP), forming a horizon in the late Pre-Boreal of Northern Europe, the Vedde ash (also Icelandic in origin, ca 12.0 cal. ka BP) and the Laacher See tephra (in the Eifel volcanic field, ca 12.9 cal. ka BP). Major volcanoes which have been used in tephrochronological studies include Vesuvius, Hekla and Santorini. Minor volcanic events may also leave their fingerprint in the geological record: Hayes Volcano is responsible for a series of six major tephra layers in the Cook Inlet region of Alaska. Tephra horizons provide a synchronous check against which to correlate the palaeoclimatic reconstructions that are obtained from terrestrial records, like fossil pollen studies (palynology), from varves in lake sediments or from marine deposits and ice-core records, and to extend the limitations of carbon-14 dating.
A pioneer in the use of tephra layers as marker horizons to establish chronology was Sigurdur Thorarinsson, who began by studying the layers he found in his native Iceland. Since the late 1990s, techniques developed by Chris S. M. Turney (QUB, Belfast) and others for extracting tephra horizons invisible to the naked eye ("cryptotephra") have revolutionised the application of tephrochronology. This technique relies upon the difference between the specific gravity of the microtephra shards and the host sediment matrix. It has led to the first discovery of the Vedde ash on the mainland of Britain, in Sweden, in the Netherlands, in the Swiss Lake Soppensee and in two sites on the Karelian Isthmus of Baltic Russia. It has also revealed previously undetected ash layers, such as the hitherto unrecorded Borrobol Tephra, dated to ca. 14,400 years BP calibrated (Wastegård 2004).

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